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Một hệ thống gồm 2 nửa tế bào, mỗi nửa chứa dung dịch có điện cực được đặt bên trong, nối với nhau bởi cầu nối là muối hoặc màng bán thấm. Tế bào voltaic là tế bào bên trong có các phản ứng hóa học xảy ra tại các điện cực cung cấp điện cho mạch điện bên ngoài; tế bào điện phân là tế bào bên trong được áp điện hướng các phản ứng xảy ra tại các điện cực theo chiều ngược lại một cách tự động.

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